@Ayeshaa,
A car is travelling on a highway
Can it have a negative velocity & a positive acceleration at the same time?
Yes, it is possible if the car is moving towards the direction which is taken as negative and its speed is reducing. For example, assume that we take North as positive. The car is moving towards South. Then its velocity is negative. If the car's speed is decreasing with time, it means it acceleration is towards North, which means it has positive acceleration.
Can the car change d direction of its velocity when travelling with constant acceleration?
Are you sure the question says constant acceleration and not zero acceleration?
If it says zero acceleration, then answer is No.
If it says constant acceleration, then answer is yes. Example: Throw an object upward. Ignoring air resistance, it has constant acceleration of g (acceleration due to gravity) downward. Initially it moves upward. On reaching the top of its path, it changes direction and starts moving doward.