You won't see much of a love story here, b'cos unlike Rama & Sita, Krishna didn't spend the bulk of his time w/ Rukmini. She does have major roles in Pradhyumna's story, since she gave birth to him and he got almost immediately kidnapped, and so given this serials love for dramatizing the emotional parts, I can see her role there being stretched, dragged and milked for all it's worth. It will have a happy ending once Pradhyumna & Mayavati return to Rukmini.
Aside from that, Rukmini was the heroine of the Tulabharam episode, when she came up w/ the solution that ensured that Krishna's family wouldn't have to hand him over to Narada, as agreed by Satyabhama 😆
But other than that, no. In fact, although Rukmini was Lakshmi, according to some accounts, Satyabhama was Krishna's favorite wife, not Rukmini. I'm waiting for the Syamantaka mani episodes - 2 more marriages for Krishna there ❤️
In Krishna's life, I doubt that any woman - not even Draupadi - will feature prominently for long. Among the men, the only ones I see lasting are Balarama, and to a lesser extent, Arjun. But the prominence Revathy has gotten in this serial is completely out of proportion to her real role, although since they've got a great actress for this, I'm not complaining 😆