Ravan forced himself upon many women. He molested many women (including Vedvati). Then why did he do no such thing with Sita? The answer given below is from Valmiki Ramayan, Uttar Kand.
Kuber was Ravan's step-brother. Kuber had a son named Nalakuber. He was married to Rambha (a nymph). One day Ravan molested Rambha in spite of her repeated pleadings not to do so. When Nalakuber came to know this, he cursed Ravan that Ravan's heads would burst if he did that again with any woman.